Dispersion (Chemistry)

guillefix 4th November 2016 at 2:43pm

A dispersion is a material comprising more than one phase where at least one of the phases consists of finely divided phase domains, often in the colloidal size range, dispersed throughout a continuous phase.

A continuous phase is a phase not interrupted in space.

A dispersed phase is a phase constituted of particles of any size and of any nature dispersed in a continuous phase of a different composition.

The dispersion medium is the matrix for the dispersed phase. The dispersion medium is the continuous phase of the dispersion.

Source from IUPAC: Terminology of polymers and polymerization processes in dispersed systems (IUPAC Recommendations 2011)*.

Depending on the size of the particles in the dispersed phase we have:

  • Solution, for size less than a nanometer.
  • Colloid, for size between a nanometer and a micrometer.
  • Coarse dispersion, for a size larger than a micrometer.

"Dispersion", without adjective, is often used to refer to the colloidal regime.

Dispersion types

For phases with particles of colloidal size or larger. For smaller sizes, see solution.

MediumDispersed medium
GasLiquidSolid
Continuous mediumGasNone (because all gases are mutually miscible)Colloidal: Liquid aerosolColloidal: Solid areosol. Coarse: Dust
LiquidIf dipersed phase has enough concentration: FoamColloidal: EmulsionColloidal: Suspension
SolidPorous solid filled with gas. If dipersed phase has enough concentration: solid FoamPorous solid filled with liquid, like GelsColloidal: Solid sol, like Cranberry glass. Coarse: conglomerates

See https://en.wikipedia.org/wiki/Dispersion_(chemistry) for examples.