Physical mechanisms of osmosis

guillefix 4th November 2016 at 2:43pm

Physical mechanisms of Osmosis

Macroscopic/thermodynamic description

Based on Chemical potentials, Solution (Chemistry)

The solution-diffusion model: a review

Microscopic mechanism

MECHANISM OF OSMOTIC FLOW IN POROUS MEMBRANES

The standard chemical potential explanation still holds as part of the mechanism. See here. The energy comes from the expansion of the solute (which works like an ideal gas), just like in quasistatic adiabatic expansion.

However, the boundary layer given by a Diffusio-osmotic effect, enhances the checmical potential difference at the pore increasing the osmotic pressure. The extra work done in the process, I think, ultimately comes from the fact that the potential energy near the wall is lowered as the solute concentration decreases during the process.

When membrane is semi-permeable (as in Osmosis proper), then I think that the main effect would be an excluded volume effect (this appears to be indeed the case, at least for purely semi-impermeable membranes see Negative osmosis), giving rise to an effective repulsive potential, like that in Nelson's Biological physics book, or those that appear in Diffusio-osmosis, or Diffusiophoresis.

See Interfacial forces

Molecular mechanisms of osmosis Mechanism of osmosis

OSMOSIS: A MACROSCOPIC PHENOMENON, A MICROSCOPIC VIEW

Osmosis is not driven by water dilution, here too. See Nelson's Biological physics book for more details

The mechanism is based on the wall repelling the solute molecules. See analysis here.

Alternative mechanisms: Osmosis, colligative properties, entropy, free energy and the chemical potential Osmosis and thermodynamics explained by solute blocking http://www.circle4.com/biophysics/chapters/BioPhysCh05.pdf

Brownian motion, hydrodynamics, and the osmotic pressure

Molecular Understanding of Osmosis in Semipermeable Membranes

See also Negative osmosis for more resources.

Osmotic pressure or decompression?